For me, The Dark Knight Rises.
I have goosebumps while watching some of the scenes. Like Batman's first appearance or the Batman v/ Bane brawl, or even the absolutely stunning pre title sequence with the plane hijack.
And even the ending feels really great and impactful, because Nolan's storytelling ties the beginning with the end.
But if you really start deconstructing the movie it falls apart.
I think it's the one time where Nolan was just too ambitious in telling his story (like in The Prestige, though it worked there better).
[SPOILER]
The Talia reveal just does not work, Bane's death is so disappointing for a character like him, Catwoman's motivations never really embrace, the stupid cops running against guys with guns, the whole giant bomb plot...
It has so many powerful scenes, but it's great peaces, with bad pieces, that don't work together.
What's a movie FOR YOU that feels great when you watch it but falls apart after you start deconstructing and thinking about it?